新型磁选装置的研制及其应用于分离超贫磁铁矿中的磁性铁   总被引：1，自引：1，他引：0  

黄瑞成  肖洁  魏灵巧  罗磊  付胜波 《岩矿测试》2015,34(2):213-217

磁性铁是超贫磁铁矿勘查中的基本分析项目之一,为准确测定磁性铁的含量,首先需要实现磁性铁的定量分离。目前常用的手工内磁选法由于所用磁铁的有效磁场强度难以保证,而且受人为操作的影响较大,导致分析结果的重现性差。本文应用50 m L滴定管、电磁铁和三相异步电动机,研制了一种新型磁选装置——电磁式磁性铁分选装置,实现了超贫磁铁矿中磁性铁与非磁性铁的定量分离,结合重铬酸钾容量法建立了超贫磁铁矿中磁性铁的分析方法。在选定的磁选条件下(电流2.5 A,磁选管运动频率40 r/min,磁选时间5 min)分析铁矿石标准物质,磁性铁的测定值与标准值的相对误差小于1.0%;分析采自实际矿区的超贫磁铁矿样品,磁性铁的测定结果与手工内磁选法一致,且相对标准偏差(RSD,n=5)小于1.0%,优于手工内磁选法的精密度。本方法采用的电磁式磁性铁分选装置有效地控制了磁场强度的强弱,避免永磁铁出现磁损失,同时可以量化磁性铁分离的参数,提高了磁性铁的分析精度。  相似文献   

灼烧法中有机质与总有机碳换算关系的重建及其在页岩分析中的应用   总被引：4，自引：3，他引：1  

邱灵佳  黄国林  帅琴  苏玉 《岩矿测试》2015,34(2):218-223

有机质与总有机碳(TOC)的换算关系为wo=1.724×wTOC,难以满足当前页岩气开发的现场测定要求,需要作出修正。本文以鄂尔多斯盆地南部页岩样品为研究对象,在传统灼烧法基础上,采用X射线荧光光谱仪测定页岩组成,得出影响烧失量的因素;用热重-差热仪研究页岩灼烧情况,确定了无机盐不分解而有机质分解的最佳灼烧温度和时间。通过线性拟合灼烧法测得的有机质含量与仪器法测得的有机碳含量间的换算关系,建立了一种通过测定烧失量来换算总有机碳含量的新方法。在页岩最佳灼烧温度480℃,灼烧时间1.5 h条件下线性拟合建立了两种新的换算关系,获得TOC测定值与仪器法的标准值相对误差分别为1.691%、0.486%,检出限分别为0.41%、1.60%。综合它们的优缺点,可将测定页岩类样品的换算关系重建为wo=2.125×wTOC。重建的方法通过严格控制灼烧温度,解决了传统灼烧法中烧失量因无机盐高温分解造成有机质代表性不足的问题,可用于精确测定页岩中的有机质或有机碳含量。  相似文献   

Predominance of archaea-derived hydrocarbons in an Early Triassic microbialite     

《Organic Geochemistry》2015

We investigated the distribution of lipids in Lower Triassic sedimentary rocks (252–247 myr) from South China, including a shallow water microbialite in the uppermost section of the outcrop. Archaeal derived hydrocarbons were the major constituents of the microbialite from the latest Early Triassic. Among these, we detected (i) abundant C₄₀ acyclic and monocyclic biphytanes (possibly derived from glycerol dialkyl glycerol tetraether lipids) and their degradation products, C_30–39 pseudohomologues and (ii) a C₂₅ head-to-tail linked (regular) isoprenoid hydrocarbon [possibly derived from dialkyl glycerol diether lipids (DGDs)] and its degradation products, C_21–24 pseudohomologues and abundant pristane and phytane. Through combination of compound-specific stable carbon isotope analysis of isoprenoid hydrocarbons, which had average δ¹³C values of −35‰ to −30‰, and their molecular distribution, it was not possible to unambiguously define the archaeal source for the biphytanes in the microbialite. The δ¹³C values for pristane and phytane were similar to those for head-to-tail linked C_21–25 isoprenoids; potential source organisms for these compounds were halophilic archaea. Except for methane seep microbialites, no other ancient or recent phototrophic microbialites have been reported to contain predominantly archaeal isoprenoid hydrocarbons. Our findings suggest the presence of a new type of microbialite.  相似文献   

Organic matter preservation in the carbonate matrix of a recent microbial mat – Is there a ‘mat seal effect’?     

《Organic Geochemistry》2015

Phototrophic mats (microbial mats with a phototrophic top layer) are complex systems in terms of microbial diversity, biogeochemical cycles and organic matter (OM) turnover. It has been proposed that these mats were a predominant life form in Proterozoic shallow water settings, prior to the emergence of bioturbating organisms in the Ediacaran–Cambrian transition. For most of the Precambrian, microbial mats were not only quantitative important carbon fixing systems, but also influenced the transfer and transformation of OM before it entered the geosphere. The profound alteration of compound inventories during transit through microbial mats, implying substantial consequences for OM preservation in the Proterozoic, was recently proposed as a “mat-seal effect” [Pawlowska et al. (2012) Geology 41, 103–106]. To obtain a better understanding of the early diagenetic fate of primary produced OM in microbial mats, we studied a recent calcifying mat from a hypersaline lake in Kiritimati, which showed in the deeper mat layers a maximum ¹⁴C_carbonate age of ∼1500 years. We particularly focused on OM entrapped in the carbonate matrix, because of the better potential of such biomineral-encapsulated OM to reach the geosphere before degradation (and remineralization). Our data indicate that selective preservation is important in phototrophic mats. While a diagenetic transformation of lipid fatty acids (FAs) was evident, their fatty acyl-derived hydrocarbon moieties were not introduced into protokerogen, which was instead mainly comprised of cyanobacterial and/or algal biomacromolecules. Our data support the proposed major impact of the “mat-seal effect” on OM turnover and preservation; i.e. the suppression of biosignatures derived from the upper mat layers, while signals of heterotrophic microbes thriving in deeper mat layers become preferentially preserved (e.g. high hopane/sterane ratios). This mechanism may have broad consequences for the interpretation of biomarkers from Proterozoic shelf environments, because biosignatures of phototrophic mat dwellers as well as planktonic signals may have become heavily biased by the production and turnover of OM in microbial mat systems.  相似文献   

Molybdenite Re–Os,zircon U–Pb dating and Hf isotopic analysis of the Shuangqing Fe–Pb–Zn–Cu skarn deposit,East Kunlun Mountains,Qinghai Province,China     

《Ore Geology Reviews》2015

The Shuangqing Fe–Pb–Zn–Cu deposit is located in the Xiangride County of Qinghai Province, China, and is a typical example of skarn deposits in the East Kunlun Mountains. Skarnization and mineralization took place along the contact zone between Carboniferous carbonates and the concealed Triassic plagiogranite. LA–ICP–MS U–Pb dating of zircons from the plagiogranite has yielded ages of 227.2 ± 1.0 and 226.54 ± 0.97 Ma, which are interpreted as the emplacement age of the plagiogranite. Molybdenites separated from ore-bearing quartz-veins yielded a Re–Os isochron age of 226.5 ± 5.1 Ma. These age data confirm that both intrusion and related skarn mineralization initiated at ~ 227 Ma. Re contents of molybdenite, zircon ε_Hf(t) and ¹⁷⁶Hf/¹⁷⁷Hf values fall into the ranges 3.31 to 6.58 μg/g, − 8.6 to − 0.0, and 0.282403 to 0.28263850, respectively. The timing of the Shuangqing Fe–Pb–Zn–Cu mineralization coincided with a major change in the stress field in East Kunlun from transpression to extension, related to the partial melting of thickening crustal materials in a post-collisional tectonic setting.  相似文献   

Mineralogical and geochemical studies of brecciated ores in the Dalucao REE deposit,Sichuan Province,southwestern China     

《Ore Geology Reviews》2015

The Dalucao deposit, located in western Sichuan Province, southwestern China, in the western part of the Yangtze Craton, is one of the largest and most extensive rare earth element (REE) deposits in the Himalayan Mianning–Dechang REE belt. Moreover, the Dalucao deposit is the only deposit identified in the southern part of the belt. The Dalucao deposit contains the No. 1, 2, and 3 orebodies; the No. 1 and 3 orebodies are both hosted in two breccia pipes, located in syenite–carbonatite host rocks. Both pipes have elliptical cross-sections at the surface, with long-axis diameters of 200–400 m and short-axis diameters of 180–200 m; the pipes extend downwards for > 450 m. No. 1 and No. 3 have total thickness varying between 55 and 175 m and 14 to 58 m respectively. The REE mineralization is associated with four brecciation events, which are recorded in each of the pipes. The ore grades in the No. 1 and 3 orebodies are similar, and consist of 1.0%–4.5% rare earth oxides (REOs). The No. 1 orebody is characterized by a Type I mineral assemblage (fluorite + barite + celestite + bastnäsite), whereas the No. 3 orebody is characterized by a Type II assemblage (fluorite + celestite + pyrite + muscovite + bastnäsite + strontianite). Argon (⁴⁰Ar/³⁹Ar) dating of hydrothermal muscovite intergrown with REE minerals in typical ores from the No. 1 and 3 orebodies yielded similar ages of 12.69 ± 0.13 and 12.23 ± 0.21 Ma, respectively, which suggest that both mineral assemblages formed coevally, rather than in paragenetic stages. Both ages are also similar to the timing of intrusion of the syenite–carbonatite complex (12.13 ± 0.19 Ma). The ore-mineral assemblages occur in breccias, veinlets, and in narrow veins. The ore veinlets, which usually show a transition to mineralized breccia or brecciated ores, are commonly enveloped by narrow veins and stringer zones with comparable mineral assemblages. The brecciated ores form 95% of the volume of the deposit, whereas brecciated ores are only a minor constituent of other deposits in the Mianning–Dechang REE belt. The carbonatite in the syenite–carbonatite complexes contains high concentrations of S (0.07–2.32 wt.%), Sr (16,500–20,700 ppm), Ba (3600–8400 ppm), and light REEs (LREE) (2848–10,768 ppm), but is depleted in high-field-strength elements (HFSE) (Nb, Ta, P, Zr, Hf, and Ti). The syenite is moderately enriched in large-ion lithophile elements (LILE), Sr (155–277 ppm), and Ba (440–755 ppm). The mineralized, altered, and fresh syenites and carbonatites exhibit similar trace element compositions and REE patterns. Brecciation events, and the Dalucao Fault and its secondary faults around the deposit, contributed to the REE mineralization by facilitating the circulation of ore-forming fluids and providing space for REE precipitation. Some hydrothermal veins composed of coarse-grained fluorite and quartz are distributed in the syenite–carbonatite complex. The oxygen isotope compositions of ore-forming fluids in equilibrium with quartz at 215 °C are − 4.95‰ to − 7.45‰, and the hydrogen isotope compositions of fluid inclusions in coarse-grained quartz are − 88.4‰ to − 105.1‰. The syenite–carbonatite complex and carbonatite are main contributors to the mineralization in the geological occurrence. Thus, the main components of the ore-forming fluids were magmatic water, meteoric water, and CO₂ derived from the decarbonation of carbonatite. According to the petrographic studies, bastnäsite mineralization developed during later stages of hydrothermal evolution and overprinted the formation of the brecciated fluorite–quartz hydrothermal veins. As low-temperature isotope exchange between carbonates of the carbonatite and water-rich magmatic fluids will lead to positive shifts in δ¹⁸O values of the carbonates, C–O isotopic compositions from the bulk primary carbonatite to hydrothermal calcite and bastnäsite changed (δ¹⁸O_V-SMOW from 8.0‰ to 11.6‰, and δ¹³C _V-PDB from − 6.1 to − 8.7‰). According to the chemical composition of syenite and carbonatite, REE chloride species are the primary complexes for the transport of the REEs in the hydrothermal fluids, and the presence of bastnäsite and parisite means the REE were precipitated as fluorocarbonates. High contents of Sr, Ba and S in the syenite–carbonatite complex led to the deposition of large amount of barite and celestite.  相似文献   

Age and petrogenesis of Anisian magnesian alkali basalts and their genetic association with the Kafang stratiform Cu deposit in the Gejiu supergiant tin-polymetallic district,SW China     

《Ore Geology Reviews》2015

Gejiu is geographically located near Gejiu city, SW China. It is one of the largest tin-polymetallic districts in the world and contains approximately 3 million tons (Mt) of Sn and smaller quantities of Cu, Pb, and Zn. The deposit primarily yields three different types of ore: skarn-hosted ore, basalt-hosted stratiform ore, and carbonate-hosted stratiform ore. Kafang is one of the primary ore deposits in the Gejiu district and is an unusual occurrence hosted in basaltic rocks. Genetic models of the Kafang deposit suggest that it is related either to Anisian (Lower stage of Middle Triassic) Gejiu basalts or to Cretaceous Gejiu granite. In this study, we performed zircon SIMS U–Pb dating, major and trace element analyses, and Sr–Nd–Pb isotopic analyses for the Gejiu basalts and S isotopic analyses for stratiform Cu ore. Our results and previous studies are used to interpret the petrogenesis of the Gejiu basalts and the origin of the basalt-hosted stratiform Cu deposit. The SIMS zircon U–Pb analyses of the Gejiu basalts yield an age of 244.4 Ma. The trace element ratios of the Gejiu basalts are similar to those of ocean island basalt and have positive εNd(t) values (ranging from 0.6 to 2.5) and uniform (⁸⁷Sr/⁸⁶Sr)_i values (ranging from 0.70424 to 0.70488). These ratios are close to those of the Permian Emeishan flood basalt. Thus, the Gejiu basalts may represent coeval volcanisms within the plate involving remelting of the Emeishan plume head through a stress relaxation process after the main plume event. The Pb and S isotopic compositions of the Gejiu basalts and the stratiform Cu ores indicate that the source of Cu and S is primarily derived from the Gejiu basalts. However, the age of sulfide mineralization (84.2–79.6 Ma) and the age of hydrothermal alteration (85.5–81.9 Ma) are temporally consistent with the age of the Cretaceous granite emplacement (85.5–83.3 Ma). From a petrological and geochemical study, we determine that the Gejiu basalts may have been subjected to pervasive granite-related hydrothermal alteration during the emplacement of granite. These processes increase the K and Mg contents of basalt and probably caused the formation of the Cu ores. Thus, the Kafang stratiform Cu deposit can be considered as a granite-related hydrothermal deposit.  相似文献   

Prospectivity of Western Australian iron ore from geophysical data using a reject option classifier     

《Ore Geology Reviews》2015

There has recently been a rapid growth in the amount and quality of digital geological and geophysical data for the majority of the Australian continent. Coupled with an increase in computational power and the rising importance of computational methods, there are new possibilities for a large scale, low expenditure digital exploration of mineral deposits. Here we use a multivariate analysis of geophysical datasets to develop a methodology that utilises machine learning algorithms to build and train two-class classifiers for provincial-scale, greenfield mineral exploration. We use iron ore in Western Australia as a case study, and our selected classifier, a mixture of a Gaussian classifier with reject option, successfully identifies 88% of iron ore locations, and 92% of non-iron ore locations. Parameter optimisation allows the user to choose the suite of variables or parameters, such as classifier and degree of dimensionality reduction, that provide the best classification result. We use randomised hold-out to ensure the generalisation of our classifier, and test it against known ground-truth information to demonstrate its ability to detect iron ore and non-iron ore locations. Our classification strategy is based on the heterogeneous nature of the data, where a well-defined target “iron-ore” class is to be separated from a poorly defined non-target class. We apply a classifier with reject option to known data to create a discriminant function that best separates sampled data, while simultaneously “protecting” against new unseen data by “closing” the domain in feature space occupied by the target class. This shows a substantial 4% improvement in classification performance. Our predictive confidence maps successfully identify known areas of iron ore deposits through the Yilgarn Craton, an area that is not heavily sampled in training, as well as suggesting areas for further exploration throughout the Yilgarn Craton. These areas tend to be more concentrated in the north and west of the Yilgarn Craton, such as around the Twin Peaks mine (~ 27°S, 116°E) and a series of lineaments running east–west at ~ 25°S. Within the Pilbara Craton, potential areas for further expansion occur throughout the Marble Bar vicinity between the existing Spinifex Ridge and Abydos mines (21°S, 119–121°E), as well as small, isolated areas north of the Hamersley Group at ~ 21.5°S, ~ 118°E. We also test the usefulness of radiometric data for province-scale iron ore exploration, while our selected classifier makes no use of the radiometric data, we demonstrate that there is no performance penalty from including redundant data and features, suggesting that where possible all potentially pertinent data should be included within a data-driven analysis. This methodology lends itself to large scale, reconnaissance mineral explorations, and, through varying the datasets used and the commodity being targeted, predictive confidence maps for a wide range of minerals can be produced.  相似文献   

“频率匹配法”在集合降水预报中的应用研究   总被引：8，自引：1，他引：7  

李俊  杜钧  陈超君 《气象》2015,41(6):674-684

基于“频率匹配法”的思路,采用两种方法进行了集合降水预报的订正研究,一种方法是利用集合成员降水频率订正简单集合平均平滑效应的“概率匹配平均”法,另一种方法是利用实况降水频率订正集合成员降水预报系统偏差的“预报偏差订正”法,通过个例和批量试验,结果表明:(1)概率匹配平均法可以矫正简单集合平均的平滑作用所造成的小量级降水分布范围增大而强降水被削弱的负作用,这种改进对强降水区更显著,并且集合系统离散度越大这种改进也越大;但该方法对预报区域内总降水量的预报没有改进作用,不能改善预报的系统性偏差.(2)虽然预报偏差订正法对降水落区预报的改进有限,但可以订正模式降水预报的系统性误差,改进雨量预报以及集合预报系统的离散度特征和概率预报技巧;直接对集合平均预报进行偏差订正的效果优于单个成员偏差订正后的简单算术平均.(3)在对每个集合成员的降水预报进行偏差订正后,概率匹配平均仍可改善其简单平均的效果,因此在实际业务中,应该综合采用上述两种方法,以获得在消除系统性偏差的同时各量级降水分布又合理的集合平均降水预报.  相似文献   

全国自动气象站实时观测资料三级质量控制系统研制   总被引：20，自引：3，他引：17  

任芝花  张志富  孙超  刘一鸣  李俊  鞠晓慧  赵煜飞  李志鹏  张玮  李洪康  曾行吉  任晓炜  刘莹  王海军 《气象》2015,41(10):1268-1277

迄今,中国气象局已在全国建立了55000余个地面自动气象站（含国家级自动站和区域自动站）。为了促进众多台站观测资料质量提高,在实时业务中保障用户用到基本正确有效的数据,2009年底中国气象局启动了“全国自动站实时资料质量控制与综合评估系统建设”工程,旨在研制一套基本适用于全国自动站实时观测数据的质量控制技术方法,建立台站、省级、国家级资料部门的地面自动站实时资料三级质量控制与反馈业务系统。在探究自动站错误数据表现形式的基础上,研制了自动站实时观测数据质量控制技术;从业务分工与应用角度,设计建立了台站负责质量监控、省级负责质量控制和国家级主要负责质量评估的自动站实时资料三级质量控制系统。该系统已在2400多个国家级气象台站、31个省级和国家级资料部门安装部署与业务应用。通过系统建设与应用,实时上传的自动站数据质量得到明显改善。主汛期全国自动站逐小时气温、降水数据可用率分别从2009年的88%、83%提升到2012、2013年的98%左右。  相似文献